Synthesis and Characterization of Metal Complexes with 4-Methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene Sulphonamide

Kingsley John Orie; Chukwuebuka David Ike; James Udochukwu Nzeneri

doi:doi:10.11648/j.mc.20210903.11

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Synthesis and Characterization of Metal Complexes with 4-Methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene Sulphonamide

Kingsley John Orie, Chukwuebuka David Ike, James Udochukwu Nzeneri

Published in Modern Chemistry (Volume 9, Issue 3)

Received: 9 July 2021 Accepted: 21 July 2021 Published: 4 August 2021

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Abstract

4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide is an important sulphonamide derivative that houses multiple essential moieties like pyridine nucleus, benzene core and sulphonamide. The research is aimed at the synthesis of 4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide via the ditosylation of 2-aminopyridine. The ditosylated 2-aminopyridine was complexed with Zinc (II) ion and Copper (II) ion. The structural elucidations were achieved through UV–Vis, FTIR, ¹HNMR, ¹³CNMR, ESI-MS and Micro-analysis. The data of the elemental analysis agrees with the molecular masses of ESI-MS. The molar conductance revealed that all the complexes are non-electrolyte in nature. The UV-VIS electronic band of 375–362 nm was assigned to n → π* electronic transition of ligand metal charge transfer (LMCT) of zinc (II) complex while 490–358nm and 690nm were assigned to n → π* electronic transition of ligand metal charge transfer (LMCT) and d→ d to electronic transition of copper (II) complex respectively. The infrared (IR) spectra studies indicated the bond between the ligand and the transition metals. The spectra of the complexes showed an absorption shift, with the free ligand of azomethine having the absorption band of 1689.70 cm^-1 while that of the complexes, Zn (II) and Cu(II) have the absorption bands of 1674.27cm^-1and 1651.12cm^-1respectively. The complexation of 4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide may hopefully increase the biological and catalytic potential of the ligand in the pharmaceutical and chemical industries.

Published in	Modern Chemistry (Volume 9, Issue 3)
DOI	10.11648/j.mc.20210903.11
Page(s)	46-51
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

2-Aminopyridine, Complexation, Ditosylation, 4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene Sulphonamide, Synthesis

References

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Kingsley John Orie, Chukwuebuka David Ike, James Udochukwu Nzeneri. (2021). Synthesis and Characterization of Metal Complexes with 4-Methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene Sulphonamide. Modern Chemistry, 9(3), 46-51. https://doi.org/10.11648/j.mc.20210903.11

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ACS Style

Kingsley John Orie; Chukwuebuka David Ike; James Udochukwu Nzeneri. Synthesis and Characterization of Metal Complexes with 4-Methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene Sulphonamide. Mod. Chem. 2021, 9(3), 46-51. doi: 10.11648/j.mc.20210903.11

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AMA Style

Kingsley John Orie, Chukwuebuka David Ike, James Udochukwu Nzeneri. Synthesis and Characterization of Metal Complexes with 4-Methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene Sulphonamide. Mod Chem. 2021;9(3):46-51. doi: 10.11648/j.mc.20210903.11

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@article{10.11648/j.mc.20210903.11,
  author = {Kingsley John Orie and Chukwuebuka David Ike and James Udochukwu Nzeneri},
  title = {Synthesis and Characterization of Metal Complexes with 4-Methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene Sulphonamide},
  journal = {Modern Chemistry},
  volume = {9},
  number = {3},
  pages = {46-51},
  doi = {10.11648/j.mc.20210903.11},
  url = {https://doi.org/10.11648/j.mc.20210903.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.mc.20210903.11},
  abstract = {4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide is an important sulphonamide derivative that houses multiple essential moieties like pyridine nucleus, benzene core and sulphonamide. The research is aimed at the synthesis of 4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide via the ditosylation of 2-aminopyridine. The ditosylated 2-aminopyridine was complexed with Zinc (II) ion and Copper (II) ion. The structural elucidations were achieved through UV–Vis, FTIR, 1HNMR, 13CNMR, ESI-MS and Micro-analysis. The data of the elemental analysis agrees with the molecular masses of ESI-MS. The molar conductance revealed that all the complexes are non-electrolyte in nature. The UV-VIS electronic band of 375–362 nm was assigned to n → π* electronic transition of ligand metal charge transfer (LMCT) of zinc (II) complex while 490–358nm and 690nm were assigned to n → π* electronic transition of ligand metal charge transfer (LMCT) and d→ d to electronic transition of copper (II) complex respectively. The infrared (IR) spectra studies indicated the bond between the ligand and the transition metals. The spectra of the complexes showed an absorption shift, with the free ligand of azomethine having the absorption band of 1689.70 cm-1 while that of the complexes, Zn (II) and Cu(II) have the absorption bands of 1674.27cm-1 and 1651.12cm-1 respectively. The complexation of 4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide may hopefully increase the biological and catalytic potential of the ligand in the pharmaceutical and chemical industries.},
 year = {2021}
}

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TY  - JOUR
T1  - Synthesis and Characterization of Metal Complexes with 4-Methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene Sulphonamide
AU  - Kingsley John Orie
AU  - Chukwuebuka David Ike
AU  - James Udochukwu Nzeneri
Y1  - 2021/08/04
PY  - 2021
N1  - https://doi.org/10.11648/j.mc.20210903.11
DO  - 10.11648/j.mc.20210903.11
T2  - Modern Chemistry
JF  - Modern Chemistry
JO  - Modern Chemistry
SP  - 46
EP  - 51
PB  - Science Publishing Group
SN  - 2329-180X
UR  - https://doi.org/10.11648/j.mc.20210903.11
AB  - 4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide is an important sulphonamide derivative that houses multiple essential moieties like pyridine nucleus, benzene core and sulphonamide. The research is aimed at the synthesis of 4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide via the ditosylation of 2-aminopyridine. The ditosylated 2-aminopyridine was complexed with Zinc (II) ion and Copper (II) ion. The structural elucidations were achieved through UV–Vis, FTIR, 1HNMR, 13CNMR, ESI-MS and Micro-analysis. The data of the elemental analysis agrees with the molecular masses of ESI-MS. The molar conductance revealed that all the complexes are non-electrolyte in nature. The UV-VIS electronic band of 375–362 nm was assigned to n → π* electronic transition of ligand metal charge transfer (LMCT) of zinc (II) complex while 490–358nm and 690nm were assigned to n → π* electronic transition of ligand metal charge transfer (LMCT) and d→ d to electronic transition of copper (II) complex respectively. The infrared (IR) spectra studies indicated the bond between the ligand and the transition metals. The spectra of the complexes showed an absorption shift, with the free ligand of azomethine having the absorption band of 1689.70 cm-1 while that of the complexes, Zn (II) and Cu(II) have the absorption bands of 1674.27cm-1 and 1651.12cm-1 respectively. The complexation of 4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide may hopefully increase the biological and catalytic potential of the ligand in the pharmaceutical and chemical industries.
VL  - 9
IS  - 3
ER  -

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Author Information

Kingsley John Orie

Department of Pure and Industrial Chemistry, Faculty of Science, University of Port Harcourt, Port Harcourt, Nigeria
Chukwuebuka David Ike

Department of Chemistry, College of Science, Federal University of Agriculture, Makurdi, Nigeria
James Udochukwu Nzeneri

Department of Chemistry, School of Science, Federal University of Technology, Owerri, Nigeria

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Kingsley John Orie, Chukwuebuka David Ike, James Udochukwu Nzeneri. (2021). Synthesis and Characterization of Metal Complexes with 4-Methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene Sulphonamide. Modern Chemistry, 9(3), 46-51. https://doi.org/10.11648/j.mc.20210903.11

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ACS Style

Kingsley John Orie; Chukwuebuka David Ike; James Udochukwu Nzeneri. Synthesis and Characterization of Metal Complexes with 4-Methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene Sulphonamide. Mod. Chem. 2021, 9(3), 46-51. doi: 10.11648/j.mc.20210903.11

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AMA Style

Kingsley John Orie, Chukwuebuka David Ike, James Udochukwu Nzeneri. Synthesis and Characterization of Metal Complexes with 4-Methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene Sulphonamide. Mod Chem. 2021;9(3):46-51. doi: 10.11648/j.mc.20210903.11

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@article{10.11648/j.mc.20210903.11,
  author = {Kingsley John Orie and Chukwuebuka David Ike and James Udochukwu Nzeneri},
  title = {Synthesis and Characterization of Metal Complexes with 4-Methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene Sulphonamide},
  journal = {Modern Chemistry},
  volume = {9},
  number = {3},
  pages = {46-51},
  doi = {10.11648/j.mc.20210903.11},
  url = {https://doi.org/10.11648/j.mc.20210903.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.mc.20210903.11},
  abstract = {4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide is an important sulphonamide derivative that houses multiple essential moieties like pyridine nucleus, benzene core and sulphonamide. The research is aimed at the synthesis of 4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide via the ditosylation of 2-aminopyridine. The ditosylated 2-aminopyridine was complexed with Zinc (II) ion and Copper (II) ion. The structural elucidations were achieved through UV–Vis, FTIR, 1HNMR, 13CNMR, ESI-MS and Micro-analysis. The data of the elemental analysis agrees with the molecular masses of ESI-MS. The molar conductance revealed that all the complexes are non-electrolyte in nature. The UV-VIS electronic band of 375–362 nm was assigned to n → π* electronic transition of ligand metal charge transfer (LMCT) of zinc (II) complex while 490–358nm and 690nm were assigned to n → π* electronic transition of ligand metal charge transfer (LMCT) and d→ d to electronic transition of copper (II) complex respectively. The infrared (IR) spectra studies indicated the bond between the ligand and the transition metals. The spectra of the complexes showed an absorption shift, with the free ligand of azomethine having the absorption band of 1689.70 cm-1 while that of the complexes, Zn (II) and Cu(II) have the absorption bands of 1674.27cm-1 and 1651.12cm-1 respectively. The complexation of 4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide may hopefully increase the biological and catalytic potential of the ligand in the pharmaceutical and chemical industries.},
 year = {2021}
}

Copy | Download

TY  - JOUR
T1  - Synthesis and Characterization of Metal Complexes with 4-Methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene Sulphonamide
AU  - Kingsley John Orie
AU  - Chukwuebuka David Ike
AU  - James Udochukwu Nzeneri
Y1  - 2021/08/04
PY  - 2021
N1  - https://doi.org/10.11648/j.mc.20210903.11
DO  - 10.11648/j.mc.20210903.11
T2  - Modern Chemistry
JF  - Modern Chemistry
JO  - Modern Chemistry
SP  - 46
EP  - 51
PB  - Science Publishing Group
SN  - 2329-180X
UR  - https://doi.org/10.11648/j.mc.20210903.11
AB  - 4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide is an important sulphonamide derivative that houses multiple essential moieties like pyridine nucleus, benzene core and sulphonamide. The research is aimed at the synthesis of 4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide via the ditosylation of 2-aminopyridine. The ditosylated 2-aminopyridine was complexed with Zinc (II) ion and Copper (II) ion. The structural elucidations were achieved through UV–Vis, FTIR, 1HNMR, 13CNMR, ESI-MS and Micro-analysis. The data of the elemental analysis agrees with the molecular masses of ESI-MS. The molar conductance revealed that all the complexes are non-electrolyte in nature. The UV-VIS electronic band of 375–362 nm was assigned to n → π* electronic transition of ligand metal charge transfer (LMCT) of zinc (II) complex while 490–358nm and 690nm were assigned to n → π* electronic transition of ligand metal charge transfer (LMCT) and d→ d to electronic transition of copper (II) complex respectively. The infrared (IR) spectra studies indicated the bond between the ligand and the transition metals. The spectra of the complexes showed an absorption shift, with the free ligand of azomethine having the absorption band of 1689.70 cm-1 while that of the complexes, Zn (II) and Cu(II) have the absorption bands of 1674.27cm-1 and 1651.12cm-1 respectively. The complexation of 4-methyl-N-(p-methylphenylsulphonyl)-N-(pyridin-2-yl)benzene sulphonamide may hopefully increase the biological and catalytic potential of the ligand in the pharmaceutical and chemical industries.
VL  - 9
IS  - 3
ER  -

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