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The Equilibrium, Kinetics and Thermodynamics of Cu2+, Zn2+, Cd2+ and Pb2+ Sorption in Sorbents with Different Functional Groups

Received: 3 November 2017     Accepted: 13 November 2017     Published: 5 December 2017
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Abstract

The equilibrium condition and kinetics of the sorption of Cu2+, Zn2+, Cd2+ and Pb2+ ions with Amberlite İRC 748 (with iminodiacetic group, Na+), Duolite C 467 (with amino-fosfon group, Na+), Dowex MAC-3 (with carboxyl group, H+) and Amberlite İR 120 (with sulpho-group, H+) cationites have been studied and thermodynamic parameters of the processes have been calculated on the basis of data gained from the equilibrium and kinetic studies. Sorption isotherms have been organized and relevant equations have been suggested. It has been defined that the kinetics of the processes in the selected concentrations under the control of the internal diffusion. Kinetic parameters have been calculated and it has been noted that heat release and entropy reduction are managed with enthalpy factor.

Published in American Journal of Modern Physics (Volume 7, Issue 1)
DOI 10.11648/j.ajmp.20180701.12
Page(s) 14-20
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Ion Exchangers, Cu2+, Zn2+, Cd2+ and Pb2+-ions, Sorption Isotherms, Langmuir and Freundlich Models, Kinetic and Thermodynamic Parameters

References
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[6] Pehlivan Erol, Altun Turkan. The study of various parameters effecting the ion exchange of Cu2+, Zn2+, Ni2+, Cd2+ and Pb2+ from aqueous solution of Dowex 50 W synthetic resin // J. Hazardous Mater. 2006, vol. 134, №1-3, p.149-156.
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  • APA Style

    Abbasov Aliaddin Dayyanoglu, Mamedova Fizza Sadikhkizi. (2017). The Equilibrium, Kinetics and Thermodynamics of Cu2+, Zn2+, Cd2+ and Pb2+ Sorption in Sorbents with Different Functional Groups. American Journal of Modern Physics, 7(1), 14-20. https://doi.org/10.11648/j.ajmp.20180701.12

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    ACS Style

    Abbasov Aliaddin Dayyanoglu; Mamedova Fizza Sadikhkizi. The Equilibrium, Kinetics and Thermodynamics of Cu2+, Zn2+, Cd2+ and Pb2+ Sorption in Sorbents with Different Functional Groups. Am. J. Mod. Phys. 2017, 7(1), 14-20. doi: 10.11648/j.ajmp.20180701.12

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    AMA Style

    Abbasov Aliaddin Dayyanoglu, Mamedova Fizza Sadikhkizi. The Equilibrium, Kinetics and Thermodynamics of Cu2+, Zn2+, Cd2+ and Pb2+ Sorption in Sorbents with Different Functional Groups. Am J Mod Phys. 2017;7(1):14-20. doi: 10.11648/j.ajmp.20180701.12

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  • @article{10.11648/j.ajmp.20180701.12,
      author = {Abbasov Aliaddin Dayyanoglu and Mamedova Fizza Sadikhkizi},
      title = {The Equilibrium, Kinetics and Thermodynamics of Cu2+, Zn2+, Cd2+ and Pb2+ Sorption in Sorbents with Different Functional Groups},
      journal = {American Journal of Modern Physics},
      volume = {7},
      number = {1},
      pages = {14-20},
      doi = {10.11648/j.ajmp.20180701.12},
      url = {https://doi.org/10.11648/j.ajmp.20180701.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmp.20180701.12},
      abstract = {The equilibrium condition and kinetics of the sorption of Cu2+, Zn2+, Cd2+ and Pb2+ ions with Amberlite İRC 748 (with iminodiacetic group, Na+), Duolite C 467 (with amino-fosfon group, Na+), Dowex MAC-3 (with carboxyl group, H+) and Amberlite İR 120 (with sulpho-group, H+) cationites have been studied and thermodynamic parameters of the processes have been calculated on the basis of data gained from the equilibrium and kinetic studies. Sorption isotherms have been organized and relevant equations have been suggested. It has been defined that the kinetics of the processes in the selected concentrations under the control of the internal diffusion. Kinetic parameters have been calculated and it has been noted that heat release and entropy reduction are managed with enthalpy factor.},
     year = {2017}
    }
    

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    T1  - The Equilibrium, Kinetics and Thermodynamics of Cu2+, Zn2+, Cd2+ and Pb2+ Sorption in Sorbents with Different Functional Groups
    AU  - Abbasov Aliaddin Dayyanoglu
    AU  - Mamedova Fizza Sadikhkizi
    Y1  - 2017/12/05
    PY  - 2017
    N1  - https://doi.org/10.11648/j.ajmp.20180701.12
    DO  - 10.11648/j.ajmp.20180701.12
    T2  - American Journal of Modern Physics
    JF  - American Journal of Modern Physics
    JO  - American Journal of Modern Physics
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    EP  - 20
    PB  - Science Publishing Group
    SN  - 2326-8891
    UR  - https://doi.org/10.11648/j.ajmp.20180701.12
    AB  - The equilibrium condition and kinetics of the sorption of Cu2+, Zn2+, Cd2+ and Pb2+ ions with Amberlite İRC 748 (with iminodiacetic group, Na+), Duolite C 467 (with amino-fosfon group, Na+), Dowex MAC-3 (with carboxyl group, H+) and Amberlite İR 120 (with sulpho-group, H+) cationites have been studied and thermodynamic parameters of the processes have been calculated on the basis of data gained from the equilibrium and kinetic studies. Sorption isotherms have been organized and relevant equations have been suggested. It has been defined that the kinetics of the processes in the selected concentrations under the control of the internal diffusion. Kinetic parameters have been calculated and it has been noted that heat release and entropy reduction are managed with enthalpy factor.
    VL  - 7
    IS  - 1
    ER  - 

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Author Information
  • Institute of Natural Resources, Nakhchivan City, Azerbaijan

  • Institute of Natural Resources, Nakhchivan City, Azerbaijan

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